He punished the children          their carelessness         making them pay for the damage.

by; for

with; by

for; by

about; with

考查介词。句意：他因为孩子们的粗心惩罚他们赔偿损失。根据句意可知：“their carelessness"表示他们被惩罚的原因，需用介词for表原因。"making them pay for the damage"表示他们被惩罚的方式，需用介词by表方式。故选C项。

It’s his brother ______ never been to Australia. You’d better take him with you.

that is

who is

that have 　

 who has

句意：就是他的弟弟从没去过澳大利亚。你最好带他和你去。根据句意及题干分析此题是考查强调句型，因为强调的是his brother，是人，所以用who引导是现在完成时态，故选D。

used to

used to be

used to do

was used to

考查词组和省略式，used to do“过去常常’,be used to do “被用来做”，句意是：--你现在是志愿者吗？--不但我过去是，去年我为市运动会工作。可以排除D项，因为这是省略句，完整的是I used to be a volunteer。英语中如果不定式的部分是重复上文可以省略to后面的内容，但是如果to后面是be动词或助动词have，就不省略。选B。