The old rules have to be          because they only applied to the circumstances that existed when they were made a hundred years ago.

developed

established

observed

revised

考查动词的辨析。句意：老的规则需要被修改因为它们只适合一百年制定时的状况。A.develop发展；培养；B.establish建立；C.observe观察；D.revise修改，由because they only applied to 可知它只适用于以前，需要修改。故选D项。

______about wild plants that they decided to make a trip to Madagascar for further research.

So curious the couple was

So curious were the couple

How curious the couple were

The couple was such curious

There                   in the world              China is a great country with a long history and rich culture.

are no doubt; that 

are not doubts; if

is no doubt; that

is not doubt; if

考查固定句型和同位语从句。句意：毫无疑问，中国是世界上有着悠久历史，丰富文化的一个大国。分析句子可知，这个句型为 there is no doubt that 引导，表示“毫无疑问......”.本句为that that 引导的同位语从句，句意和句子结构完整。故选C项。

Daniel has undertaken to keep the secret, so he won’t tell anyone even though ______.

asked to keep

to be asked

to ask

asked to

考查省略和过去分词。句意：丹尼尔答应保守这个秘密，所以即使问他也不会告诉任何人。此处是even though引导的让步状语从句，从句主语和主句主语都是he，和ask之间是被动关系，相同的主语和be动词可以省略，所以这里是过去分词作状语，且ask sb. to do sth.可以省略与前面相同的部分，只留下动词不定式符号to。故选D。

Great amounts of water            poured into the river from the factories two years ago.

was

were

has been

have been

考查时态和主谓一致。句意：两年前，工厂将大量废水排入河中。根据two years ago 可知，句子使用一般过去时。....amounts of修饰不可数名词作主语时，谓语动词用复数形式，即谓语动词与amounts保持数的一致。故选B项。